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Shes not on the list of potential spouses at http://www.uesp.net/wiki/Skyrim%3aMarriage, so that means no, it is not possible to marry her.
If you are using a pc its
Through the console (adds selected NPC to the marriage faction). Might be glitchy, but probably not with Caroletta.
I can actually marry her. I wore the amulet of mara. then when I talked to her, she said something likeis that the amulet of mara? Then there is also an option saying interested in me, are you? I dont know if its just me, and no, I did not use the console command.
You cannot marry her. I have tried, but she just says no, but I recommend marrying Aela the Huntress
In order to marry Carlotta and adopt Mila, the Dragonborn must talk to Mikael on Carlottas behalf and become a thane of Whiterun. Then put on an Amulet of Mara and talk to Carlotta wearing it. Advertisement
21 How To Get Married In Skyrim
Before players can get married in Skyrim, they need to speak with Maramal. He can be found in Riften, giving a speech at the Bee and Barb when the player first arrives in the city, or at the Temple of Mara. Ask him about marriage in Skyrim to unlock the dialogue option for marriage.
After speaking with Maramal, players need to get their hands on an Amulet of Mara and equip it before speaking with a potential spouse. The dialogue option for marriage will only appear if the spouses personal quest has been completed, so make sure to help them first with whatever they need to get done.
For those looking for a spouse in Skyrim who focuses on keeping the household together, Gilfre is the one to speak with. Shes a lumberjack by trade and an Imperial woman who will take a liking to the Dragonborn after theyve accepted her quest to chop some wood for her.
To find her, head over to the Mixwater Mill, which can be found south from Windhelm by following the river that carves through Eastmarch towards the Rift. Make sure to have a woodcutters axe on hand to chop some wood and sell it to her to complete her quest.
FAQ
Is Carlotta Marriable Skyrim?
What happens if Carlotta Valentia dies?